A Three-Dimensional Open-Framework Tin(II) Sulfate with Near-Unity Photoluminescence Quantum Yield.

Xuemei WenJing WangZhizhuan ZhangXiangyu HanHongmei ZengGuo-Hong Zou Dingguo Xu Zhi'en Lin

Published in: Inorganic chemistry (2024)

A new open-framework tin(II) sulfate, formulated as C 4 H 12 N 2 ·Sn(SO 4 ) 2 ·H 2 O, was prepared under the structure-directing effect of piperazine. This compound features a 3D structure with 16-ring channels. Under ultraviolet light irradiation, it emits bright yellow luminescence with a near-unity photoluminescence quantum yield. Theoretical calculations were carried out to understand the luminescence mechanism.

Keyphrases

energy transfer
quantum dots
light emitting
molecular dynamics
minimally invasive
density functional theory
monte carlo
molecular dynamics simulations
perovskite solar cells
radiation induced
radiation therapy