A New Class of Molecular Electrocatalysts for Hydrogen Evolution: Catalytic Activity of M3N@C2n (2n = 68, 78, and 80) Fullerenes.
Alain R Puente SantiagoMohamed Fathi SanadAntonio Moreno-VicenteMd Ariful AhsanMaira R CerónYang-Rong YaoSreeprasad T SreenivasanAntonio Rodriguez-ForteaJosep-Maria PobletLuis A EchegoyenPublished in: Journal of the American Chemical Society (2021)
The electrocatalytic properties of some endohedral fullerenes for hydrogen evolution reactions (HER) were recently predicted by DFT calculations. Nonetheless, the experimental catalytic performance under realistic electrochemical environments of these 0D-nanomaterials have not been explored. Here, for the first time, we disclose the HER electrocatalytic behavior of seven M3N@2n (2n = 68, 78, and 80) fullerenes (Gd3N@Ih(7)-C80, Y3N@Ih(7)-C80, Lu3N@Ih(7)-C80, Sc3N@Ih(7)-C80, Sc3N@D5h(6)-C80, Sc3N@D3h(5)-C78, and Sc3N@D3(6140)-C68) using a combination of experimental and theoretical techniques. The non-IPR Sc3N@D3(6140)-C68 compound exhibited the best catalytic performance toward the generation of molecular hydrogen, exhibiting an onset potential of -38 mV vs RHE, a very high mass activity of 1.75 A·mg-1 at -0.4 V vs RHE, and an excellent electrochemical stability, retaining 96% of the initial current after 24 h. The superior performance was explained on the basis of the fused pentagon rings, which represent a new and promising HER catalytic motif.