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Magnetocaloric efficiency tuning through solvent-triggered 3D to 2D interconversion in holmium(III)-based dynamic MOFs.

Nadia El Alouani DahmouniMarta Orts-ArroyoAdrián Sanchis-PeruchoNicolás MolinerJúlia MayansMario PachecoIsabel CastroGiovanni De MunnoNadia MarinoRafael Ruiz-GarcíaJose Martínez-Lillo
Published in: Chemical communications (Cambridge, England) (2024)
The neutral holmium(III) oxalate octadecahydrate {[Ho 2 (ox) 3 (H 2 O) 6 ]·12H 2 O} n of mixed hexagonal/decagonal (6 3 ·10 3 ) 3D net topology shows important changes in the magnetocaloric efficiency upon dehydration/rehydration by heating and water vapor exposition to give the holmium(III) oxalate decahydrate {[Ho 2 (ox) 3 (H 2 O) 6 ]·4H 2 O} n of hexagonal (6 3 ) 2D net topology through the intermediacy of the elusive amorphous anhydrous compound {Ho 2 (ox) 3 } n .
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