Self-Template Synthesis of Prussian Blue Analogue Hollow Polyhedrons as Superior Sodium Storage Cathodes.

Prussian blue and its analogues with three-dimensional frame structures have been shown to be of great importance in the research and development of sodium-ion batteries (SIBs). Herein, we develop a simple and convenient self-template method to prepare a hollow-structured Prussian blue analogue (CoFe-PBA). This structure is conducive to buffer the volume changes during ion extraction and insertion processes and shorten the ion diffusion path. When further building a thin polydopamine (PDA) coating, the synthesized CoFe-PBA@PDA exhibits a high discharge capacity of 123.1 mAh g-1 at 0.1 A g-1 with a capacity retention of 71.5% after 500 cycles. Moreover, the capacity retention of CoFe-PBA@PDA after 100 cycles is 14.3% higher than that of the two comparison samples. In addition, the reversible structure of CoFe-PBA@PDA without forming a new phase was verified by in situ X-ray diffraction. This work may provide another design idea or strategy for improving the stability of the PBA cathodes used in SIBs.