One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid.

Qijun WangJiahao YanMingchao XiaoDevaraj ManojCheng ZhongQiying LvLite YangLiangmei WuZhuoping WangLi-Hong Bao Hong-Jun GaoFei XiaoLang Jiang Shuai Wang

Published in: RSC advances (2019)

In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine-metal-terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B 3 O 3 ) linkage via the condensation of boronic acid. The obtained 2D COMS with a cobalt coordination center (2D COMS-Co) showed promising p-type semiconducting properties.

Keyphrases

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