Room-temperature spin nutations in a magnetically condensed phase of [Y(pc)2]˙.
Athanassios K BoudalisJorge-Enrique Olivares-PeñaEufemio Moreno PinedaArtem FediaiWolfgang WenzelPhilippe TurekMario RubenPublished in: Chemical communications (Cambridge, England) (2021)
FID-detected nutations of the antiferromagnetic crystal form of [Y(pc)2]˙ demonstrated that its radical spin can be coherently driven in its magnetically condensed undeuterated phase and at room temperature. Liquid-helium nutations revealed additional Rabi oscillations assigned to transitions within higher-multiplicity states of finite-sized chain fragments.