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Balancing Scattering Channels: A Panoscopic Approach toward Zero Temperature Coefficient of Resistance Using High-Entropy Alloys.

Samrand ShafeieSheng GuoPaul ErhartQiang HuAnders E C Palmqvist
Published in: Advanced materials (Deerfield Beach, Fla.) (2018)
Designing alloys with an accurate temperature-independent electrical response over a wide temperature range, specifically a low temperature coefficient of resistance (TCR), remains a big challenge from a material design point of view. More than a century after their discovery, Constantan (Cu-Ni) and Manganin (Cu-Mn-Ni) alloys remain the top choice for strain gauge applications and high-quality resistors up to 473-573 K. Here, an average TCR is demonstrated that is up to ≈800 times smaller in the temperature range 5-300 K and >800 times smaller than for any of these standard materials over a wide temperature range (5 K < T < 1200 K). This is achieved for selected compositions of Alx CoCrFeNi high-entropy alloys (HEAs), for which a strong correlation of the ultralow TCR is established with the underlying microstructure and its local composition. The exceptionally low electron-phonon coupling expected in these HEAs is crucial for developing novel devices, e.g., hot-electron detectors, high-Q resonant antennas, and materials in gravitational wave detectors.
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