Cooperative cage hybrids enabled by electrostatic marriage.

A cage hybrid (C-Cage-PB) was developed by electrostatic complexation of a quaternary ammonium cage (C-Cage + ) and an anionic inorganic Prussian blue (PB - ). Given the unique synergy of the two parts, such a cage hybrid can be used as a promising platform for the efficient removal of toxic compounds in wastewater through adsorption, delivery or catalytic degradation via a Fenton oxidation reaction. In addition, C-Cage-PB can encapsulate Pd clusters, which amplifies the function of the hybrid for enhanced catalytic performance in the sequential degradation of toxic organic compounds and heavy metal pollution in wastewater treatment.