Proceeding of catalytic water splitting on Cu/Ce@g-C 3 N 4 photocatalysts: an exceptional approach for sunlight-driven hydrogen generation.

Increasing energy demands and environmental problems require carbon-free and renewable energy generation systems. For this purpose, we have synthesized efficient photocatalysts ( i.e. , g-C 3 N 4 , Cu@g-C 3 N 4 , Ce@g-C 3 N 4 and Cu/Ce@g-C 3 N 4 ) for H 2 evolution from water splitting. Their optical, structural and electrochemical properties were investigated by UV-Vis-DRS, PL, XRD, FTIR, Raman and EIS methods. Their surface morphologies were evaluated by AFM and SEM analyses. Their chemical characteristics, compositions and stability were assessed using XPS, EDX and TGA techniques. Photoreactions were performed in a quartz reactor (150 mL/Velp-UK), whereas hydrogen generation activities were monitored using a GC-TCD (Shimadzu-2014/Japan). The results depicted that Cu/Ce@g-C 3 N 4 catalysts are the most active catalysts that deliver 23.94 mmol g -1 h -1 of H 2 . The higher rate of H 2 evolution was attributed to the active synergism between Ce and Cu metals and the impact of surface plasmon electrons (SPEs) of Cu that were produced during the photoreaction. The rate of H 2 production was optimized by controlling various factors, including the catalyst amount, light intensity, pH, and temperature of the reaction mixture. It has been concluded that the current study holds promise to replace the conventional and costly catalysts used for hydrogen generation technologies.