Microstructure and dynamics of Janus particles in a phase separating medium.
Enrico Federico SemeraroRajeev DattaniTheyencheri NarayananPublished in: The Journal of chemical physics (2018)
The evolution of interactions and dynamics of Janus colloidal particles suspended in quasi-binary liquid mixtures undergoing phase separation is presented. The experimental system consisted of silica-nickel Janus particles dispersed in mixtures of 3-methylpyridine, water, and heavy water. Colloidal microstructure and dynamics were probed by ultra-small-angle X-ray scattering and ultra-small-angle X-ray photon correlation spectroscopy, respectively. The observed static and dynamic behaviors are significantly different from those found for Stöber silica colloids in this mixture. The Janus particles manifest a slow aggregation below the coexistence temperature and become strongly attractive upon phase separation of the solvent mixture. In the two-phase region, particles tend to display surfactant-like behavior with silica and nickel surfaces likely preferring water and 3-methylpyridine rich phases, respectively. While the onset of diffusiophoretic motion is evident in the dynamics, it is gradually suppressed by particle clustering at the investigated colloid volume fractions.