Flexible and Highly Conductive Textiles Induced by Click Chemistry for Sensitive Motion and Humidity Monitoring.

To date, multifunctional sensors have aroused widespread concerns owing to their vital roles in the healthcare area. However, there are still significant challenges in the fabrication of functionalized integrated devices. In this work, hydrophobic-hydrophilic patterns are constructed on polyester-spandex-blended knitted fabric surface by the chemical click method, enabling accurate deposition of functionalized materials for sensitive and stable motion and humidity sensing. Representatively, a conductive silver nanowire (Ag NW) network was deliberately deposited on only the designated hydrophilic fabric surface to realize accurate, repeatable, and stable motion sensing. Such a Ag NWs sensor recorded a low electrical resistance (below 60 Ω), stable resistance cycling response (over 2000 cycles), and fast response time to humidity (0.46 s) during the sensing evaluation. In addition to experimental sensing, real human motions, such as mouth-opening and joint-flexing (wrist and neck), could also be detected using the same sensor. Similar promising outputs were also obtained over the humidity sensor fabricated over the same chemical click method, except the sensing material was replaced with polydopamine-modified carboxylated carbon nanotubes. The resultant sensor exhibits excellent sensitivity to not only experimentally adjusted environment humidity but also to the moisture content of breath and skin during daily activities. On top of all these, both sensors were fabricated over highly flexible fabric that offers high wearability, promising great application potential in the field of healthcare monitoring.