Bottom-Up Synthesis of Twisted Porous Graphene through a Heterogeneous Scholl Reaction and Its Supercapacitor Application.
Sahina KhatunSiddhartha SamantaMatthew A AddicoatAnirban PradhanPublished in: ACS applied materials & interfaces (2024)
Anthracene- and pyrene-based twisted porous graphene ( AN-Pyre-PG ) with an ordered pore structure has been synthesized through bottom-up solution phase synthesis from a conjugated microporous polymer ( AN-Pyre-CMP ) via a heterogeneous Scholl cyclization reaction. The regular-ordered pores embedded within the graphene structures were analyzed through a Raman spectrum, different morphological analyses, and theoretical studies. A significant change in surface area from AN-Pyre-CMP to AN-Pyre-PG was observed, from 143 to 640 m 2 /g, respectively. Surface area-driven capacitive properties were also observed. Twisted-structure and ordered porous graphene shows better specific capacitance compared to CMP. AN-Pyre-PG shows a specific capacitance of 629 F g -1 at 1 A g -1 , with 91% retention of capacitance after 3000 charge-discharge cycles, whereas AN-Pyre-CMP shows a maximum specific capacitance of 200 F g -1 was observed at 2 A g -1 .