On-surface reactions of aryl chloride and porphyrin macrocycles via merging two reactive sites into a single precursor.

Chen-Hui ShuYu-Li XieAn WangKe-Ji ShiWei-Feng ZhangDeng-Yuan LiPei Nian Liu

Published in: Chemical communications (Cambridge, England) (2018)

The reaction of aryl chloride and porphyrin macrocycles, which are merged into a single precursor, has been achieved on Cu(111). Scanning tunneling microscopy analysis of the oligomer products showed that the adjacent porphyrin moieties linked mainly by the phenyl group with the porphyrin macrocycle.

Keyphrases

photodynamic therapy
metal organic framework
electron transfer
energy transfer
high resolution
single molecule
high throughput
high speed
electron microscopy
mass spectrometry
single cell