Login / Signup

Carbaporphyrin Dimers That Bear a Rigid Naphthalene Motif as an Internal Strap.

Jung-Ho HongAdil S AslamBeomhee ChoMin-Sung KoYounghoon KimJungseok HeoDong-Gyu Cho
Published in: Organic letters (2021)
The first fully connected aromatic carbaporphyrin dimer (6) and its bis-Pd complex (6-Pd2) that bear a rigid naphthalene motif as an internal strap were synthesized. These dimers consisted of two aromatic carbaporphyrins that shared a naphthalene motif. The π-electron conjugation of the obtained macrocycles was proposed to have two separated local 22 π-electron pathways and a 34 π-electron pathway. Their weak aromaticity was fully supported by 1H NMR spectroscopy, NICS values, ACID calculations, and ICSS plots.
Keyphrases
  • solar cells
  • amino acid
  • electron microscopy
  • electron transfer
  • molecular dynamics simulations
  • molecular dynamics