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Organo metal halide perovskites effectively photosensitize the production of singlet oxygen (1Δg).

Xian-Fu ZhangBaomin Xu
Published in: Chemical communications (Cambridge, England) (2019)
Using the steady state and time resolved NIR emission and specific chemical trapping techniques, we show for the first time that metal halide perovskite quantum dots can effectively generate singlet oxygen with a quantum yield of up to 0.34, the highest among nano semiconductor/nano metal singlet oxygen photosensitizers. The mechanism is concluded to be due to energy transfer from triplet excitons to molecular oxygen.
Keyphrases
  • energy transfer
  • quantum dots
  • photodynamic therapy
  • solar cells
  • room temperature
  • sensitive detection
  • drug delivery
  • molecular dynamics
  • fluorescence imaging