MOF (UiO-66-NH 2 )@COF (TFP-TABQ) hybrids via on-surface condensation reactions for sustainable energy storage.

Dawid PakulskiVerónica Montes-GarcíaWłodzimierz CzepaDawid MarcinkowskiHaijun PengTomasz ChudziakAdam GorczyńskiWojciech KukułkaCataldo Valentini Violetta Patroniak Paolo Samorì Artur Ciesielski

Published in: Chemical communications (Cambridge, England) (2023)

Core-shell MOF@COF hybrids were synthesized via subsequent modification of MOF UiO-66-NH 2 with 1,3,5-triformylphloroglucinol (TFP) and 2,3,5,6-tetraaminobenzoquinone (TABQ). The hybrids exhibited significant surface area (236 m 2 g -1 ) and outstanding electrochemical performance (103 F g -1 at 0.5 A g -1 ), surpassing both COFs and MOFs, thereby showcasing the potential of on-surface condensation reactions for developing high-performance energy storage devices.

Keyphrases

metal organic framework
room temperature
gold nanoparticles
ionic liquid
risk assessment
climate change
human health
perovskite solar cells
tandem mass spectrometry