Multifunctional Electrocatalysis on a Porous N-Doped NiCo2O4@C Nanonetwork.

Developing a multifunctional electrocatalyst with eminent activity, strong durability, and cheapness for the hydrogen/oxygen evolution reaction (HER/OER) and oxygen reduction reaction (ORR) is critical to overall water splitting and regenerative fuel cells. Herein, a nitrogen-doped nanonetwork assembled by porous and defective NiCo2O4@C nanowires grown on nickel foam (N-NiCo2O4@C@NF) is crafted via biomimetic mineralization and following carbonization of phase-transited lysozyme (PTL)-coupled NiCo2O4. The as-obtained N-NiCo2O4@C@NF electrocatalysts exhibit an exceptional catalytic activity with ultralow overpotentials for the HER (42 mV) and OER (242 mV) to afford 10 mA cm-2 while maintaining good stability in alkaline media. Meanwhile, the N-NiCo2O4@C electrocatalysts presents a superior catalytic activity for ORR and a favorable four-electron pathway. The unprecedented catalytic performance arises from a highly porous structure and abundant defects and synergistic effects of components. This work may offer a new possibility in the exploration of multifunctional electrocatalysts for various energy-related electrocatalytic reactions.