Metallaaromatics show a diversity of aromaticity. In this work, we report the synthesis and structural characterization of the first rhena-phenalene complexes. In addition to the Hückel aromaticity and σ-aromaticity, pseudo π anti-aromaticity is observed. DFT computations show that this anti-aromaticity (paramagnetic properties) is induced by the fused aromatic naphthyl ring.
Keyphrases