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Unraveling the physiochemical nature of colloidal motion waves among silver colloids.

Xi ChenYankai XuChao ZhouKai LouYixin PengH P ZhangWei Wang
Published in: Science advances (2022)
Traveling waves are common in biological and synthetic systems, including the recent discovery that silver (Ag) colloids form traveling motion waves in H 2 O 2 and under light. Here, we show that this colloidal motion wave is a heterogeneous excitable system. The Ag colloids generate traveling chemical waves via reaction-diffusion, and either self-propel through self-diffusiophoresis ("ballistic waves") or are advected by diffusio-osmotic flows from gradients of neutral molecules ("swarming waves"). Key results include the experimental observation of traveling waves of OH - with pH-sensitive fluorescent dyes and a Rogers-McCulloch model that qualitatively and quantitatively reproduces the key features of colloidal waves. These results are a step forward in elucidating the Ag-H 2 O 2 -light oscillatory system at individual and collective levels. In addition, they pave the way for using colloidal waves either as a platform for studying nonlinear phenomena, or as a tool for colloidal transport and for information transmission in microrobot ensembles.
Keyphrases
  • quantum dots
  • gold nanoparticles
  • small molecule
  • mass spectrometry
  • high throughput
  • high speed
  • visible light