Spontaneous Growth of 3D Silver Mesoflowers on Poly(4-vinylpyridine) Brushes-Grafted-Graphene Oxide Films and Facile Creation of Nanoporosities over their Surface.

Fabricating three-dimensional (3D) hierarchical noble-metal particles by spontaneous redox reactions between graphene and noble-metal salts still remains a great challenge. Herein, the fact that graphene oxide (GO) itself acts as both a platform for grafting polymer brushes and a reducing agent to reduce [Ag(NH3 )2 ]+ ions is taken advantages of. 3D flower-like Ag mesoparticles (Ag mesoflowers, Ag MFs) with tunable size and shapes can spontaneous grow on poly(4-vinylpyridine) brushes-grafted-graphene oxide (P4VP-g-GO) films in Ag(NH3 )2 OH solution without the use of any additional reducing agent. The residual Ag(NH3 )2 OH on 3D Ag MFs surface can be further reduced by NaBH4 , causing abundant nanoporosities over the entire Ag MFs. The resulting Ag nanoporous MFs (Ag NMFs) with larger surface-to-volume ratio and higher nanoscale roughness exhibit ultrasensitivity in surface-enhanced Raman spectroscopy (SERS) detection, and the detection limit for 4-aminothiophenol is as low as 10-13  m.