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Fabrication of Na-Ion Full-Cells using Carbon-Coated Na 3 V 2 (PO 4 ) 2 O 2 F Cathode with Conversion Type CuO Nanoparticles from Spent Li-Ion Batteries.

Krishnan SubramanyanManohar AkshayYun-Sung LeeVanchiappan Aravindan
Published in: Small methods (2022)
Spent lithium-ion batteries (LIBs) offer immense potential in the form of resources such as Li, transition metals (Co, Ni, and Mn), graphite, and Cu, which can be recovered through suitable recycling procedures. The Cu-current collector is recovered from spent LIBs and converted as a copper oxide (CuO) anode for Na-ion batteries. The performance of CuO is evaluated with carboxymethyl cellulose (CMC) (CuO-C), and polyvinylidene fluoride (PVdF) (CuO-P) binders in CuO half-cell and CuO/carbon-coated Na 3 V 2 (PO 4 ) 2 O 2 F (CuO/NVPOF) full-cell assemblies. The CuO-C half-cell displays superior electrochemical performance than CuO-P in terms of cycling and rate performance showing 88% more capacity. To study the stabilization and solid electrolyte interphase growth in CuO-C, an in situ impedance study is conducted. However, the full-cell, CuO-P/NVPOF displays better capacity retention during cycling with Coulombic efficiency >95% from the second cycle, whereas CuO-C/NVPOF could hardly maintain only >90%. For conversion type CuO, it is apparent that, though the CMC binder supports half-cell performance, the PVdF binder is suitable for the practical cell/full-cell configuration.
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