Quantum dots assembled from an aziridinium based hybrid perovskite displaying tunable luminescence.
Oleksandr A SemenikhinOlesia I KucherivLiviu SacarescuSergiu ShovaIl'ya A Gural'skiyPublished in: Chemical communications (Cambridge, England) (2023)
3D hybrid perovskites based upon small organic cations gave start to a new intensively growing class of semiconducting materials. Here we report on the elaboration of quantum dots of a recently emerged new perovskite (AzrH)PbBr 3 (AzrH = aziridinium cation). By employing the antisolvent precipitation technique and stabilization with a cationic surfactant we succeeded in obtaining quantum dots that display tunable luminescence. This piece of work shows the perspective of aziridinium-based materials for the elaboration of advanced photonic nanostructures.