Co(II)-Chelated Polyimines as Oxygen Reduction Reaction Catalysts in Anion Exchange Membrane Fuel Cells.
Yu-Chang HuangYen-Zen WangTar-Hwa HsiehWen-Yao HuangPublished in: Membranes (2023)
In this paper, a cobalt (Co)-chelated polynaphthalene imine (Co-PNIM) was calcined to become an oxygen reduction reaction (ORR) electrocatalyst (Co-N-C) as the cathode catalyst (CC) of an anion exchange membrane fuel cell (AEMFC). The X-ray diffraction pattern of CoNC-1000A900 illustrated that the carbon matrix develops clear C(002) and Co(111) planes after calcination, which was confirmed using high-resolution TEM pictures. Co-N-Cs also demonstrated a significant ORR peak at 0.8 V in a C-V (current vs. voltage) curve and produced an extremely limited reduction current density (5.46 mA cm -2 ) comparable to commercial Pt/C catalysts (5.26 mA cm -2 ). The measured halfway potential of Co-N-C (0.82 V) was even higher than that of Pt/C (0.81 V). The maximum power density (P max ) of the AEM single cell upon applying Co-N-C as the CC was 243 mW cm -2 , only slightly lower than that of Pt/C (280 mW cm -2 ). The Tafel slope of CoNC-1000A900 (33.3 mV dec -1 ) was lower than that of Pt/C (43.3 mV dec -1 ). The limited reduction current density only decayed by 7.9% for CoNC-1000A900, compared to 22.7% for Pt/C, after 10,000 redox cycles.
Keyphrases
- single cell
- high resolution
- metal organic framework
- highly efficient
- ionic liquid
- reduced graphene oxide
- induced apoptosis
- rna seq
- magnetic resonance imaging
- high throughput
- room temperature
- oxidative stress
- stem cells
- magnetic resonance
- signaling pathway
- risk assessment
- transition metal
- mesenchymal stem cells
- endoplasmic reticulum stress
- carbon nanotubes