Chiral double stapled o-OPEs with intense circularly polarized luminescence.

Pablo ReineAraceli G Campaña Luis Álvarez de Cienfuegos Victor Blanco Sergio Abbate Antonio J Mota Giovanna Longhi Delia Miguel Juan Manuel Cuerva

Published in: Chemical communications (Cambridge, England) (2019)

Intrinsically chiral double stapled ortho-oligo phenylene ethynylenes (o-OPEs) 1 show glum values up to 5.5 × 10-2, the second highest value ever observed for a simple organic molecule (SOM). DFT calculations of molecular spectra and properties encompassing electric and magnetic dipole transition moments account for these observations.

Keyphrases

density functional theory
capillary electrophoresis
molecular dynamics
ionic liquid
quantum dots
molecular dynamics simulations
molecularly imprinted
single molecule
mass spectrometry
energy transfer
water soluble