Metal Ions Redox Induced Repeatable Nonvolatile Resistive Switching Memory Behavior in Biomaterials.

The resistance random access memory (RRAM) based on biomaterials has great potential application in the sustainable electronic devices with the advantages of being sustainable, green, and environment-friendly, and it can offer a potential route for developing bio-RRAM devices, which would be a competitive bench in development of multipurpose memory devices. In our work, the banana peel, an ubiquitous useless waste, is introduced as an intermediate insulating material to preparing resistive switching memory device with Ag/Banana peel/Ti structure, in which the superior switching memory performance with a lager high resistance state/low resistance state resistance ratio and long retention characteristics are revealed. Moreover, the coexistence of memristor effect, capacitance effect, and negative differential resistance phenomenon are observed in our device. The repeatable nonvolatile resistive switching memory behaviors are attributed to the redox properties of metal cations contained in biomaterials.