Login / Signup

Bis[tris-(pyridin-2-yl)amine]-iron(II) tris-(di-cyano-methyl-idene)methane-diide.

Zouaoui SetifiFatima SetifiNecmi DegeMohammed Hadi Al-DouhChristopher Glidewell
Published in: IUCrData (2020)
In the title compound, [Fe{(C 5 H 4 N) 3 N} 2 ][C{C(CN) 2 } 3 ], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate and 32 symmetry, respectively, and the Fe-N bond lengths indicate low-spin Fe II . A combination of two-centre C-H⋯N and three-centre C-H⋯(N) 2 hydrogen bonds link the ions into complex sheets. Several low-occupancy water mol-ecules are present, whose H atoms could not be located: accordingly, the reflection data were subjected to the SQUEEZE procedure [Spek (2015 ▸). Acta Cryst. C 71 , 9-18].
Keyphrases