Comment on "Realization of Lewis Basic Sodium Anion in the NaBH3 - Cluster".
Sudip PanGernot FrenkingPublished in: Angewandte Chemie (International ed. in English) (2020)
We challenge the interpretation of the chemical bond in NaBH3 - proposed by Liu et al. We argue that NaBH3 - has an electron-sharing Na-BH3 - covalent bond rather than a dative bond Na- →BH3 .