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Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine: Involving Formation of S2 and T2 States.

Ryoichi IshimatsuHirosato ShintakuYuto KageMisaki KamiokaSoji ShimizuKoji NakanoHiroyuki FurutaToshihiko Imato
Published in: Journal of the American Chemical Society (2019)
Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S2 and T2 states through the electron transfer reaction, which affects the ECL efficiencies.
Keyphrases
  • electron transfer
  • sensitive detection
  • mass spectrometry
  • quantum dots
  • liquid chromatography