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Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field.

Tsuneomi KawasakiYoshiyasu KaimoriSeiya ShimadaNatsuki HaraSusumu SatoKenta SuzukiToru AsahiArimasa MatsumotoKenso Soai
Published in: Chemical communications (Cambridge, England) (2021)
Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
Keyphrases
  • solid state
  • capillary electrophoresis
  • nucleic acid
  • ionic liquid
  • single molecule
  • water soluble