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Presodiation Architected Robust Surface Enables Packaging Optimal Performance of Sodium-Ion Batteries.

Meiqi LiuWenwen LiFuxi LiuWei Zhang
Published in: Nano letters (2024)
Presodiation has shown great promise in compensating sodium storage losses. In the absence of a mechanistic understanding of how presodiation affects the surface of an electrode material, packaging optimization is restricted. Focusing on interfaces, we illustrate the working principle of presodiation in virtue of short-circuiting internal circuits. The presodiated carbon nanotubes (PS-CNTs) provide a thin, denser, and more robust solid electrolyte interfacial layer, enabling a high initial Coulombic efficiency (ICE), high power density, and cycling stability with the merits of uniformly distributed NaF. As a result, our assembled sodium-ion battery (SIB) full cell with PS-CNT has an ICE of 91.6% and an energy density of 226 Wh kg -1 , which was superior to the pristine CNT control electrode (ICE of 42.9% and energy density of 163 Wh kg -1 ). The gained insights can be practically applied to directly promote the commercial uses of carbon-based materials in sodium-ion batteries.
Keyphrases
  • ion batteries
  • carbon nanotubes
  • ionic liquid
  • single cell
  • high intensity
  • cell therapy
  • machine learning
  • big data
  • deep learning
  • artificial intelligence
  • walled carbon nanotubes