Visible-Light-Mediated Sulfonylimination of Tertiary Amines with Sulfonylazides Involving Csp3-Csp3 Bond Cleavage.

Jiao GuiHaisheng XieHuan-Feng Jiang Wei Zeng

Published in: Organic letters (2019)

Visible-light-induced cross-coupling of arylsulfonyl azides with tertiaryamines in the presence of Eosin Y at room temperature has been achieved. This transformation features alkyl C-C bond cleavage and provides a green approach to N-sulfonylamidines under mild conditions.

Keyphrases

visible light
room temperature
ionic liquid
dna binding
transition metal
transcription factor