Enhancement of intermolecular aggregation on solvent-influenced strong hydrogen-bonded single crystal.
Kanthapazham RajakumarNadezhda S NekorysnovaPavel V DorovatovskiiArtyom A OsipovSergei A NayfertAndrey N EfremovDaniel SanthanarajVanaraj RamkumarDmitry S TolstoguzovDmitry A ZherebtsovPublished in: Luminescence : the journal of biological and chemical luminescence (2024)
The intermolecular aggregation between the solvent and organic molecules is covered in the current article. 4,4'-(Buta-1,3-diyne-1,4-diyl)dibenzoic acid (DADBA) was used as an organic molecule and dimethyl sulfoxide (DMSO) as a solvent to create the target compound DADBA-DMSO. The material's hydrogen bonding and intermolecular aggregation were determined by appropriate characterization methods, including single-crystal X-ray diffraction (XRD), Fourier-transform infrared (FTIR), photoluminescence (PL), and cyclic voltammetry (CV) analysis. Each hydrogen of the carboxylic group is coordinated by oxygen from the DMSO molecule in the stiff planar layer packing that makes up the DADBA-DMSO crystal structure.