Spiroborate-Based Host Materials with High Triplet Energies and Ambipolar Charge-Transport Properties.

Organic light-emitting diodes (OLEDs) receive considerable attention because of their commercial use in flat panel displays. Herein, highly efficient spiroborate-based host materials are reported for use in blue OLEDs. Our designed spiroborates (SBOX) were simple to synthesize and exhibited high triplet excitation energies, narrow S-T gaps, and balanced charge carrier mobilities. A blue OLED containing one of the designed spiroborates, SBON, as a host exhibited a high external quantum efficiency (27.6 %) and low turn-on voltage (3.7 V) compared to those observed using 3,3'-di(9H-carbazol-9-yl)-1,1'-biphenyl (17.6 % and 4.5 V, respectively), indicating their potential as host materials in OLEDs.