Login / Signup

Reply to the Correspondence on "How Aromatic Are Molecular Nanorings? The Case of a Six-Porphyrin Nanoring".

Irene Casademont-ReigLuis Soriano-AguedaEloy Ramos-CordobaMiquel Torrent-SucarratEduard Matito
Published in: Angewandte Chemie (International ed. in English) (2022)
A recent article by Anderson and co-workers challenges our conclusions on the aromaticity of the four oxidation states of a butadyine-linked six-porphyrin nanoring, based on the experimental 1 H-NMR data and some recent calculations they have performed using the BLYP35 functional. Here, we show that BLYP35 should be taken with caution and demonstrate that the indirect evidence of a ring current from experimental 1 H-NMR data is not a definite proof of aromaticity.
Keyphrases