Preparation and characterisation of heterobimetallic copper-tungsten hydride complexes.
Alexandra HickenAndrew J P WhiteMark R CrimminPublished in: Dalton transactions (Cambridge, England : 2003) (2018)
The preparation and structural characterisation of three new heterobimetallic hydride complexes containing 3-centre,2-electron W-H-Cu bonds is reported. These complexes have been characterised by single crystal X-ray crystallography and multinuclear NMR spectroscopy. The bonding in these complexes has been analysed by DFT calculations.