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Effects of Lanthanum Substitution and Annealing on Structural, Morphologic, and Photocatalytic Properties of Nickel Ferrite.

Thomas DippongDana TolomanMihaela Diana LazarIoan Petean
Published in: Nanomaterials (Basel, Switzerland) (2023)
Nanoparticles of NiLa x Fe 2-x O 4 ferrite spinel incorporated in a SiO 2 matrix were synthesized via a sol-gel method, followed by annealing at 200, 500, and 800 °C. The resulting materials were characterized via XRD, AFM, and BET techniques and evaluated for photocatalytic activity. The XRD diffractograms validate the formation of a single-phase cubic spinel structure at all temperatures, without any evidence of secondary peaks. The size of crystallites exhibited a decrease from 37 to 26 nm with the substitution of Fe 3+ with La 3+ ions. The lattice parameters and crystallite sizes were found to increase with the rise in La 3+ content and annealing temperature. Isotherms were employed to calculate the rate constants for the decomposition of malonate precursors to ferrites and the activation energy for each ferrite. All nanocomposites have pores within the mesoporous range, with a narrow dispersion of pore sizes. The impact of La content on sonophotocatalytic activity was evaluated by studying Rhodamine B degradation under visible light irradiation. The results indicate that the introduction of La enhances nanocomposite performance. The prepared Ni-La ferrites may have potential application for water decontamination.
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