Effect of Electrode/Electrolyte Coupling on Birnessite (δ-MnO 2 ) Mechanical Response and Degradation.
Wan-Yu TsaiShelby B PillaiKarthik GaneshanSaeed SaeedYawei GaoAdri C T van DuinVeronica AugustynNina Balke WisingerPublished in: ACS applied materials & interfaces (2023)
Understanding the deformation of energy storage electrodes at a local scale and its correlation to electrochemical performance is crucial for designing effective electrode architectures. In this work, the effect of electrolyte cation and electrode morphology on birnessite (δ-MnO 2 ) deformation during charge storage in aqueous electrolytes was investigated using a mechanical cyclic voltammetry approach via operando atomic force microscopy (AFM) and molecular dynamics (MD) simulation. In both K 2 SO 4 and Li 2 SO 4 electrolytes, the δ-MnO 2 host electrode underwent expansion during cation intercalation, but with different potential dependencies. When intercalating Li + , the δ-MnO 2 electrode presents a nonlinear correlation between electrode deformation and electrode height, which is morphologically dependent. These results suggest that the stronger cation-birnessite interaction is the reason for higher local stress heterogeneity when cycling in Li 2 SO 4 electrolyte, which might be the origin of the pronounced electrode degradation in this electrolyte.