Nickel(II)-Doped Lead-Free Halide Crystals Exhibiting Highly Efficient Tunable Blue-Emitting out of Antiferromagnetic Ni-Ni Coupling.

Metal halide crystals are widely used in optoelectronic fields due to their excellent optical properties. The hunt for a lead-free halide semiconductor with superior optical performance is a particularly fascinating topic in order to avoid the toxicity of lead. Here, we incorporate Ni 2+ into a series of halide nanocrystals (NCs) through solution-phase synthesis. By modifying the A-site and varying the halide compositions, we successfully achieved significant tunability of the blue emission of the Ni 2+ -doped AX (A = K + , Rb + , NH 2 CH = NH 2 + (FA), CH 3 NH 3 + (MA); X = Br, I) NCs, ranging from 375 to 490 nm, due to the antiferromagnetic polaron (AMP), which is in contrast with the excitonic magnetic polarons (EMP) from those with ferromagnetic (FM) coupling between transition metal ions in similar compounds. This work shows that Ni 2+ -doped halide crystals could become a typical example providing AMP excitation as the optional emission centers for use in light emitting devices.