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Hybrid Hemp Particles as Functional Fillers for the Manufacturing of Hydrophobic and Anti-icing Epoxy Composite Coatings.

Jessica PassaroAurelio BifulcoElisa CalabreseClaudio ImparatoMarialuigia RaimondoRoberto PantaniAntonio AronneLiberata Guadagno
Published in: ACS omega (2023)
The development of hydrophobic composite coatings is of great interest for several applications in the aerospace industry. Functionalized microparticles can be obtained from waste fabrics and employed as fillers to prepare sustainable hydrophobic epoxy-based coatings. Following a waste-to-wealth approach, a novel hydrophobic epoxy-based composite including hemp microparticles (HMPs) functionalized with waterglass solution, 3-aminopropyl triethoxysilane, polypropylene-graft-maleic anhydride, and either hexadecyltrimethoxysilane or 1 H ,1 H ,2 H ,2 H -perfluorooctyltriethoxysilane is presented. The resulting epoxy coatings based on hydrophobic HMPs were cast on aeronautical carbon fiber-reinforced panels to improve their anti-icing performance. Wettability and anti-icing behavior of the prepared composites were investigated at 25 °C and -30 °C (complete icing time), respectively. Samples cast with the composite coating can achieve up to 30 °C higher water contact angle and doubled icing time than aeronautical panels treated with unfilled epoxy resin. A low content (2 wt %) of tailored HMPs causes an increase of ∼26% in the glass transition temperature of the coatings compared to pristine resin, confirming the good interaction between the hemp filler and epoxy matrix at the interphase. Finally, atomic force microscopy reveals that the HMPs can induce the formation of a hierarchical structure on the surface of casted panels. This rough morphology, combined with the silane activity, allows the preparation of aeronautical substrates with enhanced hydrophobicity, anti-icing capability, and thermal stability.
Keyphrases
  • atomic force microscopy
  • ionic liquid
  • aqueous solution
  • hyaluronic acid
  • heavy metals
  • quantum dots
  • molecularly imprinted
  • high resolution
  • life cycle
  • newly diagnosed
  • liquid chromatography
  • visible light