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Experimental and theoretical insights into Co-Ln magnetic exchange and the rare slow-magnetic relaxation behavior of [CoII2Pr] 2+ in a series of linear [CoII2Ln] 2+ complexes.

Naushad AhmedKamal Uddin Ansari
Published in: Dalton transactions (Cambridge, England : 2003) (2022)
We herein report a series of near-linear trinuclear complexes [Co 2 Ln(HL) 4 (NO 3 )](NO 3 ) 2 (where HL = (2-methoxy-6-[( E )-2'-hydroxymethyl-phenyliminomethyl]-phenolate) with Ln(III) = La (1), Ce (2), Pr (3)). For the comparative study, we have also included the recently reported analogous complexes of Gd(III), Tb(III), and Dy(III) (complexes 4-6) with the same H 2 L ligand. The experimental nature of the dc magnetic susceptibilities profile and an empirical approach revealed that the magnetic exchange interaction between Co(II) and Ln(III) having <4f 7 (complexes 2 and 3) is antiferromagnetic while the dominant interaction between Co(II) and Ln(III) having ≥4f 7 (complexes 4-6) is ferromagnetic. Dynamic magnetic relaxation studies on complexes 1-3 revealed the field induced single-molecule magnetic (SMM) behavior of 1 and 3 with effective energy barriers of 10.65 K and 15.03 K respectively, for magnetic relaxation. To the best of our knowledge, 3d-Pr(III) based zero or field induced SMMs have not been reported to date. CASSCF/SO-RASSI/SINGLE_ANISO based ab initio calculations on the X-ray structures of complexes 1-6, followed by POLY_ANISO simulations, estimated the magnetic exchange coupling constants J Co-Ln and J Co-Co and also rationalized our experimental findings for the dynamic magnetic properties.
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