Tailor Traps in Bi 3+ -Doped NaGdGeO 4 Phosphors by Introducing Eu 3+ Ions to Switch Multimodal Phosphorescence Emission.

Featured with a tunable excitation/emission wavelength and excellent physicochemical stability, inorganic fluorescent materials are widely used in the fields of anti-counterfeiting. Here, we design a multi-stimuli-responsive dynamic fluorescence and phosphorescence anti-counterfeiting material by introducing Eu 3+ ions in NaGdGeO 4 : Bi 3+ to tailor the trap structure. The photoluminescence (PL), long persistent luminescence (LPL), and photo-stimulated luminescence (PSL) colors of NaGdGeO 4 : Bi 3+ , Eu 3+ can be switched by varying the excitation modes (ultraviolet, near infrared, and X-ray light). Especially, the LPL and PSL colors of NaGdGeO 4 : Bi 3+ , Eu 3+ vary with increasing decay and stimulation times. In addition, X-ray excitation ensures the specificity of the luminescence of NaGdGeO 4 : Bi 3+ , Eu 3+ compared with ultraviolet excitation. This rapidly-changing-color fluorescent material offers the possibility of sophisticated anti-counterfeiting applications in the future.