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Boric acid-destabilized lithium borohydride with a 5.6 wt% dehydrogenation capacity at moderate temperatures.

Yong WuXiaojing JiangJun ChenYue QiYuxuan ZhangHe FuJie ZhengXingguo Li
Published in: Dalton transactions (Cambridge, England : 2003) (2018)
Boric acid effectively promotes the dehydrogenation of lithium borohydride due to the interactions between protonic and hydridic hydrogen. The simple mixture of LiBH4-(4/3)B(OH)3 can release 5.6 wt% hydrogen below 180 °C with only a trace amount of water, thus constituting a highly attractive single-use hydrogen storage material.
Keyphrases
  • visible light
  • solid state
  • risk assessment