Local Field Induced Mass Transfer: New Insight into Nano-electrocatalysis.

Unravelling the complex kinetics of electrocatalysis is essential for the design of electrocatalysts with high performance. Mass transfer and electron transfer are two primary factors that need to be optimized in order to enhance electrocatalytic reactions. The use of nanocatalysts proves to be a promising way of promoting the performance of electrocatalytic reactions, this improvement is usually attributed to their ability to enhance electron transfer. However, when catalysts are taken down to the nanoscale, their size is comparable to the thickness of an electrical double layer, so any curvature can lead to an inhomogeneous local electric field on the electrode, which then changes the mass transfer essentially. In this article, we introduce the new concept of local-field-induced mass transfer in nano-electrocatalytic systems, and provide a brief review of recent progress, revealing its effect on nano-electrocatalysis, which may bring new insight into the future design of nano-electrocatalysts.