Double-Wavelength-Switchable Molecular Self-Assembly of a Photoacid and Spirooxazine in an Aqueous Solution.

Quadruple-switchable nanoscale assemblies are built by combining two types of water-soluble molecular photoswitches through dipole-dipole interaction. Uniting the wavelength-specific proton dissociation of a photoacid and ring-opening of an anionic spirooxazine results in an assembly that can be addressed by irradiation with two different wavelengths: pH and darkness.