Login / Signup

Direct observation of Ru-alkylidene forming into ethylene in ring-closing metathesis from hyperpolarized 1H NMR.

Yaewon KimChia-Hsiu ChenChristian Hilty
Published in: Chemical communications (Cambridge, England) (2018)
Ring-closing metathesis was monitored using real-time NMR of 1H hyperpolarized olefins at room temperature. By applying a selective saturation to an observable intermediate, its protons were found to transfer to ethylene. The intermediate was thus identified as a Ru-alkylidene species, which appears in the ethylene formation pathway.
Keyphrases
  • room temperature
  • magnetic resonance
  • high resolution
  • solid state
  • ionic liquid
  • energy transfer