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Crystal structure and Hirshfeld surface analysis of ( Z )-4-({[2-(benzo[ b ]thio-phen-3-yl)cyclo-pent-1-en-1-yl]meth-yl}(phen-yl)amino)-4-oxobut-2-enoic acid.

Elizaveta D YakovlevaEvgeniya R ShelukhoMikhail Semenovich GrigorievKhudayar I HasanovNurlana D SadikhovaMehmet AkkurtAjaya Bhattarai
Published in: Acta crystallographica. Section E, Crystallographic communications (2024)
In the title compound, C 24 H 21 NO 3 S, the cyclopentene ring adopts an envelope conformation. In the crystal, mol-ecules are linked by C-H⋯π inter-actions, forming ribbons along the a axis. Inter-molecular C-H⋯O hydrogen bonds connect these ribbons to each other, forming layers parallel to the (01) plane. The mol-ecular packing is strengthened by van der Waals inter-actions between the layers. The inter-molecular contacts were qu-anti-fied using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative contributions of the contacts to the crystal packing to be H⋯H 46.0%, C⋯H/H⋯C 21.1%, O⋯H/H⋯O 20.6% and S⋯H/H⋯S 9.0%.
Keyphrases
  • crystal structure