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Selective recovery of zinc from goethite residue in the zinc industry using deep-eutectic solvents.

Nerea Rodriguez RodriguezLieven MachielsBieke OnghenaJeroen SpoorenKoen Binnemans
Published in: RSC advances (2020)
Several deep-eutectic solvents (DESs) were tested for the valorisation of goethite residue produced by the zinc industry. The objective of the work was to selectively recover zinc from the iron-rich matrix using deep-eutectic solvents as lixiviants. The effect of the type of hydrogen bond donor and hydrogen bond acceptor of the deep-eutectic solvent on the leaching efficiency was studied. Levulinic acid-choline chloride ( x ChCl = 0.33) (LevA-ChCl) could selectively leach zinc from the iron-rich matrix, and it was selected as the best-performing system to be used in further study. The leaching process was optimised in terms of temperature, contact time, liquid-to-solid ratio and water content of the deep-eutectic solvent. The role of the choline cation on the leaching process was investigated by considering the leaching properties of a LevA-CaCl 2 mixture. The goethite residue was also leached with pure levulinic acid. The results were compared to a purely hydrometallurgical approach using sulphuric acid leaching. Leaching with LevA-ChCl resulted in higher selectivity compared to the conventional "hot leaching" with 80 g L -1 sulphuric acid. Furthermore, a slightly higher zinc recovery and comparable selectivity for zinc over iron were achieved with LevA-ChCl compared to conventional "neutral leaching" with 10 g L -1 sulphuric acid.
Keyphrases
  • heavy metals
  • sewage sludge
  • municipal solid waste
  • oxide nanoparticles
  • ionic liquid
  • risk assessment
  • iron deficiency