In situ formic acid dehydrogenation observation using a UV-vis-diffuse-reflectance spectroscopy system.
Risheng LiTetsuya KodairaHajime KawanamiPublished in: Chemical communications (Cambridge, England) (2022)
By applying a simple method on the generated gas concentration in the center of a round cell through high-speed stirring, we succeeded in continuously monitoring catalytic formic acid dehydrogenation using a newly developed in situ /operando UV-vis-diffuse-reflectance spectroscopy system, which can exhibit a high S/N ratio and reliable spectra without any mechanical errors from gas meters.