Effective removal of non-steroidal anti-inflammatory drug from wastewater by adsorption process using acid-treated Fagopyrum esculentum husk.
Dison S P FrancoJordana GeorginMatias Schadeck NettoEdson L FolettoDaniel AllasiaMarcos L S OliveiraDiana PintoGuilherme Luiz DottoPublished in: Environmental science and pollution research international (2022)
In this work, buckwheat husks (Fagopyrum esculentum) were modified by acid treatment and posteriorly employed to remove the ketoprofen in batch adsorption. The characterization results indicated that a more irregular surface with new empty spaces was generated after acid treatment. The adsorptive process was favored at acidic pH = 3. The dosage of 0.85 g L -1 was fixed for the kinetic and isothermal tests, obtaining good removal and capacity indications. The kinetic studies were better represented by pseudo-second-order, obtaining an experimental capacity of 74.3 mg g -1 for 200 mg L -1 of ketoprofen. An increase in temperature negatively affected the adsorption isotherm curves, resulting in a maximum capacity of 194.1 mg g -1 . Thermodynamic results confirmed the exothermic nature of the process with physical forces acting. The adsorbent presented high efficiency in treating a synthetic effluent containing different drugs and salts, 71.2%. Therefore, adsorbent development from buckwheat husks treated with a strong acid is an excellent alternative, given the good removal results and the low cost for its preparation.