Global Alignment of Solution-Based Single-Wall Carbon Nanotube Films via Machine-Vision Controlled Filtration.
Joshua S WalkerJeffrey A FaganAdam J BiacchiValerie A KuehlThomas A SearlesAngela R Hight WalkerWilliam D RicePublished in: Nano letters (2019)
Over the past decade, substantial progress has been made in the chemical control (chiral enrichment, length sorting, handedness selectivity, and filling substance) of single-wall carbon nanotubes (SWCNTs). Recently, it was shown that large, horizontally aligned films can be created out of postprocessed SWCNT solutions. Here, we use machine-vision automation and parallelization to simultaneously produce globally aligned SWCNT films using pressure-driven filtration. Feedback control enables filtration to occur with a constant flow rate that not only improves the nematic ordering of the SWCNT films but also provides the ability to align a wide range of SWCNT types and on a variety of nanoporous membranes using the same filtration parameters. Using polarized optical spectroscopic techniques, we show that under standard implementation, meniscus combing produces a two-dimensional radial SWCNT alignment on one side of the film. After we flatten the meniscus through silanization, spatially resolved nematicity maps on both sides of the SWCNT film reveal global alignment across the entire structure. From experiments changing ionic strength and membrane charging, we provide evidence that the SWCNT alignment mechanism stems from an interplay of intertube interactions and ordered membrane charging. This work opens up the possibility of creating globally aligned SWCNT film structures for a new generation of nanotube electronics and optical control elements.